Ti
Ti
Titanum
German
Titan
English
Titanium
French
Titane
Croatian
Titanij
Italian
Titanio
Spanish
Titanio
Neighborhood
 
 
 
Sc
21
Ti
22
V
23
Y
39
Zr
40
Nb
41

PERIODIC TABLE OF THE ELEMENTS

TITANIUM

TRANSITION ELEMENT: TITANIUM GROUP

Atomic number:22

Group numbers:4

Period:4

Electronic configuration:[Ar] 3d2 4s2

Formal oxidation number:+2 +3 +4

Electronegativities:1.54

Atomic radius / pm:144.8

Relative atomic mass:47.867 ± 0.001

 

Titanium was discovered by William Gregor (GB) in 1791. Named after the Titans, the sons of the Earth goddess in Greek mythology. It is a shiny, dark-grey metal. In powdered form it burns in air. Exposed surfaces form oxide coating. It can be highly polished and is relatively immune to tarnishing. Titanium is unreactive with alkali and most acids. Titanium usually occurs in the minerals ilmenite (FeTiO3), rutile (TiO2) and iron ores. Pure metal produced by heating TiO2 with carbon and chlorine to produce TiCl4 then heated with Mg gas in argon atmosphere. Since it is strong and resists acids it is used in many alloys. Titanium dioxide (TiO2), a white pigment that covers surfaces very well, is used in paint, rubber, paper and many others.

CRYSTALLOGRAPHIC DATA
hexagonal

Crystal structure:

hexagonal

Unit-cell dimensions / pm:

a=295.11, c=468.43

Space group:

P63/mmc

 
PHYSICAL PROPERTIES

Density / g dm-3:4540 (293 K)

 4110 (m.p.)

Molar volume / cm3mol-1:10.54 (293 K)

 11.65 (m.p.)

Electrical resistivity / μΩcm:42 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:21.9

Melting point / °C:1668

Boiling point / °C:3287

Heat of fusion / kJ mol-1:20.9

Heat of vaporization / kJ mol-1:425.5

Heat of atomization / kJ mol-1:467.14

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:658.82

2nd ionization energy / kJ mol-1:1309.85

3rd ionization energy / kJ mol-1:2652.56

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:5400

in the oceans / ppm:0.001

ISOTOPES
IsotopeRelative atomic massMass percent (%)
46Ti45.952629(1)8.0(1)
47Ti46.951764(1)7.3(1)
48Ti47.947947(1)73.8(1)
49Ti48.947871(1)5.5(1)
50Ti49.944792(1)5.4(1)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
TiIV + e- = TiIII- 0.092 (1 mol dm-3 HCl)
TiIV + 4e- = Ti(s)- 0.88 (1 mol dm-3 HCl)
Ti3+ + e- = Ti2+- 0.369
Ti2+ + 2e- = Ti(s)- 1.630
TiO22+ + H+ + 4e- = HTiO2-+1.303
TiO22+ + 2H+ + 2e- = TiO2+ + H2O+1.800
TiO2(s) + 4H+ + e- = Ti3+ + H2O- 0.666
TiO2(s) + 4H+ + 2e- = Ti2+ + H2O- 0.502
TiO2+ + 2H+ + e- = Ti3+ + H2O+0.099
TiO2+ + 2H+ + e- = Ti3+ + H2O+0.04 (1 mol dm-3 H2SO4)
TiO2+ + 2H+ + 2e- = Ti2+ + H2O- 0.135
HTiO2- + 5H+ + 2e- = Ti2+ + 3H2O+0.362
TiF62- + 4e- = Ti(s) + 6F-- 1.19

 

21 Scandium <= 22 Titanium => 23 Vanadium