Zr
Zr
Zirconium
German
Zirkon
English
Zirconium
French
Zirconium
Croatian
Cirkonij
Italian
Zirconio
Spanish
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Sc
21
Ti
22
V
23
Y
39
Zr
40
Nb
41
La
57
Hf
72
Ta
73

PERIODIC TABLE OF THE ELEMENTS

ZIRCONIUM

TRANSITION ELEMENT: TITANIUM GROUP

Atomic number:40

Group numbers:4

Period:5

Electronic configuration:[Kr] 4d2 5s2

Formal oxidation number:+4

Electronegativities:1.33

Atomic radius / pm:159

Relative atomic mass:91.224 ± 0.002

 

Zirconium was discovered by Martin Heinrich Klaproth (DE) in 1789. The origin of the name comes from the Arabic word zargun meaning gold colour. It is a grey-white, lustrous, corrosion-resistant metal. Exposed surfaces form oxide protective film. Zirconium is found in many minerals such as zircon and baddeleyite. It is used in alloys such as zircaloy which is used in nuclear applications since it does not readily absorb neutrons. Zirconium is used in high-performance pumps and valves. Clear zircon (ZrSiO4) is a popular gemstone.

CRYSTALLOGRAPHIC DATA
hexagonal

Crystal structure:

hexagonal

Unit-cell dimensions / pm:

a=323.21, c=514.77

Space group:

P63/mmc

 
PHYSICAL PROPERTIES

Density / g dm-3:6506 (293 K)

 5800 (m.p.)

Molar volume / cm3mol-1:14.02 (293 K)

 15.73 (m.p.)

Electrical resistivity / μΩcm:42.1 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:22.7

Melting point / °C:1855

Boiling point / °C:4409

Heat of fusion / kJ mol-1:23

Heat of vaporization / kJ mol-1:566.7

Heat of atomization / kJ mol-1:607.47

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:640.08

2nd ionization energy / kJ mol-1:1266.86

3rd ionization energy / kJ mol-1:2218.21

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:100

in the oceans / ppm:0.000026

ISOTOPES
IsotopeRelative atomic massMass percent (%)
90Zr89.904704(2)51.45(3)
91Zr90.905645(2)11.22(4)
92Zr91.905040(2)17.15(2)
94Zr93.906316(3)17.38(4)
96Zr95.908276(3)2.80(2)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
Zr4+ + 4e- = Zr(s)- 1.539
H2ZrO3(s) + H2O + 4e- = Zr(s) + 4OH-- 2.36
HZrO3- + 5H+ + 4e- = Zr(s) + 3H2O- 1.276
ZrO2+ + 2H+ + 4e- = Zr(s) + H2O- 1.570
ZrO2(s) + 4H+ + 4e- = Zr(s) + 2H2O- 1.456
ZrO2×H2O(s) + 4H+ + 4e- = Zr(s) + 3H2O- 1.533
ZrO2×2H2O + 4H+ + 4e- = Zr(s) + 4H2O- 1.553

 

39 Yttrium <= 40 Zirconium => 41 Niobium