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Tc
43
Ru
44
Rh
45
Re
75
Os
76
Ir
77
Bh
107
Hs
108
Mt
109

 

Periodic table

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Osmium

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Osmium

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Osmium

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Osmij

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Osmio

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Osmio

 

Os
Os
Osmium

PERIODIC TABLE OF THE ELEMENTS

OSMIUM

TRANSITION ELEMENT:
IRON GROUP

 

Atomic number:76

Group numbers:8

Period:6

Electronic configuration:[Xe] 4f14 5d6 6s2

Formal oxidation number:+3 +4

Electronegativities:2.2

Atomic radius / pm:133.8

Relative atomic mass:190.23 ± 0.03

 

Osmium was discovered by Smithson Tennant (GB) in 1803. The origin of the name comes from the Greek word osme meaning smell. It is a hard fine black powder or hard, lustrous, blue-white metal. Osmium is unaffected by air, water and acids. It has a characteristic acrid, chlorine like odour due to tetroxide compound. Osmium tetroxide is highly toxic. Osmium is obtained from the same ores as platinum. It is used to tip gold pen points, instrument pivots, to make electric light filaments, and also used for high temperature alloys and pressure bearings. Osmium is very hard and resists corrosion better than any other element.

PHYSICAL PROPERTIES

Density / g dm-3:22590 (293 K)

 20100 (m.p.)

Molar volume / cm3mol-1:8.42 (293 K)

 9.46 (m.p.)

Electrical resistivity / μΩcm:9.5 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:87.6

Melting point / °C:3033

Boiling point / °C:5012

Heat of fusion / kJ mol-1:29.3

Heat of vaporization / kJ mol-1:738.06

Heat of atomization / kJ mol-1:791

IONIZATION ENERGIES

First ionization energy / kJ mol-1:814.17

Second ionization energy / kJ mol-1:-

Third ionization energy / kJ mol-1:-

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:0.005

in the oceans / ppm:-

CRYSTALLOGRAPHIC DATA

hexagonal

Crystal structure:

hexagonal

Unit-cell dimensions / pm:

a=273.43, c=432.00

Space group:

P63/mmc

ISOTOPES

IsotopeRelative atomic massMass percent (%)
184Os183.952491(3)0.02(1)
186Os185.953838(3)1.58(30)
187Os186.955748(3)1.6(3)
188Os187.955836(3)13.3(7)
189Os188.958145(3)16.1(8)
190Os189.958445(3)26.4(12)
192Os191.961479(4)41.0(8)

REDUCTION POTENTIALS

Balanced half-reaction Eo / V
Os2+ + 2e- = Os(s)+0.85 (1 mol dm-3 HCl)
OsO2(s) + 2H2O + 4e- = Os(s) + 4OH-- 0.15
OsO4(s) + 8H+ + 8e- = Os(s) + 4H2O+0.85
OsO4(s) + 8H+ + 6Cl- + 4e- = OsCl62- + 4H2O+1.0
HOsO5- + 2e- = OsO42- + OH-+0.3
OsO42- + 2H2O + 2e- = OsO2(s) + 4OH-+0.1
OsCl62- + e- = OsCl63-+0.85
OsCl63- + e- = Os2+ + 6Cl-+0.4
OsCl63- + 3e- = Os(s) + 6Cl-+0.71

 

75 Rhenium <=
76 Osmium
=> 77 Iridium