Atomic number:23
Group numbers:5
Period:4
Electronic configuration:[Ar] 3d3 4s2
Formal oxidation number:+2 +3 +4 +5
Electronegativities:1.63
Atomic radius / pm:131.1
Relative atomic mass:50.9415 ± 0.0001
Vanadium was discovered by Andres Manuel del Rio (MX) in 1801 and rediscovered by Nils Gabriel Sefstrôm (SE) in 1830. Named after Vanadis, the goddess of beauty in Scandinavian mythology. It is a soft, ductile, silvery-white metal, resistant to corrosion by moisture, air and most acids and alkalis at room temperature. Exposed surfaces form oxide coating. It reacts with concentrated acids. Vanadium is found in the minerals patronite (VS4), vanadinite [Pb5(VO4)3Cl] and carnotite [K2(UO2)2(VO4)2.3H2O]. Pure metal produced by heating with C and Cl to produce VCl3 which is heated with Mg in Ar atmosphere. It is mixed with other metals to make very strong and durable alloys. Vanadium pentoxide (V2O5) is used as a catalyst, dye and fixer-fixer.
Density / g dm-3:6110 (292 K)
5550 (m.p.)
Molar volume / cm3mol-1:8.34 (292 K)
9.18 (m.p.)
Electrical resistivity / μΩcm:19.68 (20 °C)
Thermal conductivity / W m-1K-1:30.7
Melting point / °C:1910
Boiling point / °C:3407
Heat of fusion / kJ mol-1:17.6
Heat of vaporization / kJ mol-1:459.7
Heat of atomization / kJ mol-1:510.95
First ionization energy / kJ mol-1:650.92
Second ionization energy / kJ mol-1:1414.49
Third ionization energy / kJ mol-1:2828.10
in the atmosphere / ppm:-
in the Earth's crust / ppm:230
in the oceans / ppm:0.002
Crystal structure:
body-centered cubic
Unit-cell dimensions / pm:
a=302.40
Space group:
Im3m
| 22 Titanium <= |
23 Vanadium
|
=> 24 Chromium |