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23
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24
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41
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42
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Periodic table

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Chrom

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Chromium

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Chrome

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Krom

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Cromo

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Cromo

 

Cr
Cr
Chromum

PERIODIC TABLE OF THE ELEMENTS

CHROMIUM

TRANSITION ELEMENT: CHROMIUM GROUP

 

Atomic number:24

Group numbers:6

Period:4

Electronic configuration:[Ar] 3d5 4s1

Formal oxidation number:+2 +3 +6

Electronegativities:1.66

Atomic radius / pm:124.9

Relative atomic mass:51.9961 ± 0.0006

 

Chromium was discovered by Louis-Nicholas Vauquelin (FR) in 1797. The origin of the name comes from the Greek word chroma meaning colour. It is a very hard, crystalline, steel-grey metal. The pure metal has a blue-white colour. It is hard, brittle and corrosion-resistant at normal temperatures. Hexavalent compounds are toxic by skin contact. The most important chromium mineral is chromite [Fe,Mg(CrO4)]. It is produced commercially by heating its ore in the presence of silicon or aluminium. Chromium is used to make stainless steel; it gives the colour to rubies and emeralds. Iron-nickel-chromium alloys in various percentages yield an incredible variety of the most important metals in modern technology.

PHYSICAL PROPERTIES

Density / g dm-3:7190 (293 K)

 6460 (m.p.)

Molar volume / cm3mol-1:7.23 (293 K)

 8.05 (m.p.)

Electrical resistivity / μΩcm:12.9 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:93.7

Melting point / °C:1907

Boiling point / °C:2671

Heat of fusion / kJ mol-1:15.3

Heat of vaporization / kJ mol-1:341.8

Heat of atomization / kJ mol-1:394.51

IONIZATION ENERGIES

First ionization energy / kJ mol-1:652.87

Second ionization energy / kJ mol-1:1590.64

Third ionization energy / kJ mol-1:2987.21

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:185

in the oceans / ppm:0.00005

CRYSTALLOGRAPHIC DATA

body-centered cubic

Crystal structure:

body-centered cubic

Unit-cell dimensions / pm:

a=288.46

Space group:

Im3m

ISOTOPES

IsotopeRelative atomic massMass percent (%)
50Cr49.946050(1)4.345(13)
52Cr51.940512(2)83.789(18)
53Cr52.940654(2)9.501(17)
54Cr53.938885(1)2.365(7)

REDUCTION POTENTIALS

Balanced half-reaction Eo / V
Cr3+ + e- = Cr2+- 0.408
Cr3+ + 3e- = Cr(s)- 0.744
Cr2+ + 2e- = Cr(s)- 0.91
Cr2O72- + 14H+ + 6e- = 2Cr3+ + 7H2O+1.33
Cr2O72- + 12H+ + 6e- = 2CrOH2+ + 5H2O+1.26
Cr2O72- + 10H+ + 6e- = 2Cr(OH)2+ + 3H2O+1.14
Cr2O72- + 14H+ + 12e- = 2Cr(s) + 7H2O+0.29
HCrO4- + 7H+ + 3e- = Cr3+ + 4H2O+1.20
CrO42- + 4H2O + 3e- = Cr(OH)3(s) + 5OH-- 0.13
HCrO4- + 6H+ + 3e- = CrOH2+ + 3H2O+1.28
CrO42- + 7H+ + 3e- = CrOH2+ + 3H2O+1.40
CrO42- + 6H+ + 3e- = Cr(OH)2+ + 2H2O+1.28
CrO42- + 4H+ + 3e- = CrO2- + 2H2O+0.95
CrO42- + 2H+ + 3e- = CrO33- + H2O+0.36

 

23 Vanadium <=
24 Chromium
=> 25 Manganese