Ce
Ce
Cerium
German
Cer
English
Cerium
French
Cérium
Croatian
Cerij
Italian
Cerio
Spanish
Cerio
Neighborhood
Y
39
 
 
La
57
Ce
58
Pr
59
Ac
89
Th
90
Pa
91

PERIODIC TABLE OF THE ELEMENTS

CERIUM

TRANSITION ELEMENT: LANTHANIDE

Atomic number:58

Group numbers:3

Period:6

Electronic configuration:[Xe] 4f2 6s2

Formal oxidation number:+3 +4

Electronegativities:1.12

Atomic radius / pm:182.5

Relative atomic mass:140.116 ± 0.001

 

Cerium was discovered by Jöns Jakob Berzelius and Wilhelm Hisinger (SE) in 1803 and independently by Martin Heinrich Klaproth (DE). Named after the asteroid Ceres discovered two years before the element. It is a malleable, ductile, iron-grey metal that tarnishes in air and reacts easily with water. Cerium dissolves in acids and ignites when heated. Metal ignites and burns readily. Strong reductant. Cerium is most abundant rare earth metal. Found in many minerals like monazite sand [Ce(PO4)]. Its oxides are used in the optics and glass-making industries. Its salts are used in the photography and textile industry. Cerium is also used in high-intensity carbon lamps and as alloying agents in special metals.

CRYSTALLOGRAPHIC DATA
face-centered cubic

Crystal structure:

face-centered cubic

Unit-cell dimensions / pm:

a=485

Space group:

Fm3m

 
PHYSICAL PROPERTIES

Density / g dm-3:8240 (alpha, 298 K)

 6749 (beta, 298 K)

 6773 (gamma, 298 K)

Molar volume / cm3mol-1:17.00 (alpha, 298 K)

 20.76 (beta, 298 K)

 20.69 (gamma, 298 K)

Electrical resistivity / μΩcm:75 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:11.4

Melting point / °C:798

Boiling point / °C:3443

Heat of fusion / kJ mol-1:8.87

Heat of vaporization / kJ mol-1:398

Heat of atomization / kJ mol-1:423.4

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:534.41

2nd ionization energy / kJ mol-1:1046.87

3rd ionization energy / kJ mol-1:1948.82

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:33

in the oceans / ppm:0.0004

ISOTOPES
IsotopeRelative atomic massMass percent (%)
136Ce135.90714(5)0.19(1)
137Ce136.90778(5)*
138Ce137.90599(1)0.25(1)
139Ce138.906647(8)*
140Ce139.905434(3)88.48(10)
141Ce140.908271(3)*
142Ce141.909240(4)11.08(10)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
Ce3+ + 3e- = Ce(s)- 2.48
Ce(OH)22+ + 2H+ + e- = Ce3+ + 2H2O+1.73
Ce(OH)3+ + H+ + e- = Ce3+ + H2O+1.71
Ce(ClO4)62- + e- = Ce3+ + 6ClO4-+1.70 (1 mol dm-3 HClO4)
Ce(NO3)62- + e- = Ce3+ + 6NO3-+1.61 (1 mol dm-3 HNO3)
Ce(SO4)32- + e- = Ce3+ + 3SO42-+1.44 (1 mol dm-3 H2SO4)

 

57 Lanthanum <= 58 Cerium => 59 Praseodymium