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Ce
58
Pr
59
Nd
60
Th
90
Pa
91
U
92

PERIODIC TABLE OF THE ELEMENTS

PRASEODYMIUM

TRANSITION ELEMENT: LANTHANIDE

Atomic number:59

Group numbers:3

Period:6

Electronic configuration:[Xe] 4f3 6s2

Formal oxidation number:+3

Electronegativities:1.13

Atomic radius / pm:182

Relative atomic mass:140.90765 ± 0.00002

 

Praseodymium was discovered by Carl Freiherr Auer von Welsbach (AT) in 1885. The origin of the name comes from the Greek words prasios didymos meaning green twin. It is a silvery white, moderately soft, malleable, ductile metal that reacts slowly with oxygen but reacts rapidly with water. Metal ignites and burns readily. Praseodymium is obtained from same salts as neodymium. It is used with neodymium to make lenses for glass maker's goggles since it filters out the yellow light present in glass blowing. Alloyed with magnesium praseodymium creates a high-strength metal used in aircraft engines. Misch metal, used in the manufacture of pyrophoric alloys for cigarette lighters, contains about 5% praseodymium metal. (Typically composition of misch metal are Ce:Nd:Pr:La:Other rare earth=50:18:6:22:4).

CRYSTALLOGRAPHIC DATA
hexagonal

Crystal structure:

hexagonal

Unit-cell dimensions / pm:

a=367.25, c=1183.5

Space group:

P63/mmc

 
PHYSICAL PROPERTIES

Density / g dm-3:6773 (293 K)

Molar volume / cm3mol-1:20.80 (293 K)

Electrical resistivity / μΩcm:68 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:12.5

Melting point / °C:931

Boiling point / °C:3520

Heat of fusion / kJ mol-1:11.3

Heat of vaporization / kJ mol-1:357

Heat of atomization / kJ mol-1:356.69

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:527.20

2nd ionization energy / kJ mol-1:1017.93

3rd ionization energy / kJ mol-1:2086.41

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:3.9

in the oceans / ppm:0.0000002

ISOTOPES
IsotopeRelative atomic massMass percent (%)
141Pr140.907648(3)100
REDUCTION POTENTIALS
Balanced half-reaction Eo / V

 

58 Cerium <= 59 Praseodymium => 60 Neodymium