Pu
Pu
Plutonium
German
Plutonium
English
Plutonium
French
Plutonium
Croatian
Plutonij
Italian
Plutonio
Spanish
Plutonio
Neighborhood
Pm
61
Sm
62
Eu
63
Np
93
Pu
94
Am
95
 
 
 

PERIODIC TABLE OF THE ELEMENTS

PLUTONIUM

TRANSITION ELEMENT: ACTINIDE

Atomic number:94

Group numbers:3

Period:7

Electronic configuration:[Rn] 5f6 7s2

Formal oxidation number:+3 +4 +5 +6

Electronegativities:1.3

Atomic radius / pm:151.3

Relative atomic mass:[244]

 

Plutonium was discovered by Glenn Theodore Seaborg, Joseph W. Kennedy, and Arthur C. Wahl (US) in 1940. Named after the planet Pluto. It is a silvery-white, extremely radioactive, highly toxic, artificially produced metal that reacts with oxygen, acids and steam, but it resists alkalis. Plutonium is found rarely in some uranium ores. It can be made by bombarding uranium with neutrons. Plutonium is used in bombs and reactors. Small quantities are used in thermo-electric generators.

CRYSTALLOGRAPHIC DATA
simple monoclinic

Crystal structure:

simple monoclinic

Unit-cell dimensions / pm:

a=618.3, b=482.2, c=1096.3, β=101.79°

Space group:

P21m

 
PHYSICAL PROPERTIES

Density / g dm-3:19840 (298 K)

 16623 (m.p.)

Molar volume / cm3mol-1:12.30 (298 K)

 14.68 (m.p.)

Electrical resistivity / μΩcm:150 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:6.74

Melting point / °C:640

Boiling point / °C:3228

Heat of fusion / kJ mol-1:2.8

Heat of vaporization / kJ mol-1:343.5

Heat of atomization / kJ mol-1:348

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:581.44

2nd ionization energy / kJ mol-1:-

3rd ionization energy / kJ mol-1:-

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:-

in the oceans / ppm:-

ISOTOPES
IsotopeRelative atomic massMass percent (%)
239Pu239.052157(2)*
244Pu244.064198(5)*
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
Pu4+ + e- = Pu3++0.970
Pu3+ + 3e- = Pu(s)- 2.03
PuO22+ + 4H+ + 2e- = Pu4+ + 2H2O+1.04
PuO22+ + e- = PuO2++0.916
Pu(OH)3(s) + 3e- = Pu(s) + 3OH-- 2.42
Pu(OH)4(s) + e- = Pu(OH)3(s) + OH-- 0.95

 

93 Neptunium <= 94 Plutonium => 95 Americium