U
U
Uranium
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Pr
59
Nd
60
Pm
61
Pa
91
U
92
Np
93
 
 
 

PERIODIC TABLE OF THE ELEMENTS

URANIUM

TRANSITION ELEMENT: ACTINIDE

Atomic number:92

Group numbers:3

Period:7

Electronic configuration:[Rn] 5f3 6d1 7s2

Formal oxidation number:+3 +4 +5 +6

Electronegativities:1.7

Atomic radius / pm:138.5

Relative atomic mass:238.02891 ± 0.00003

 

Uranium was discovered by Martin Heinrich Klaproth (DE) in 1789. Named after the planet Uranus. It is a silvery-white, dense, ductile, malleable, radioactive, radiotoxic metal that resists alkalis, tarnishes in air and reacts with steam and acids. Uranium occurs in many rocks, but in large amounts only in such minerals as pitchblende and carnotite. For many centuries it was used as a pigment for glass. Now it is used as a fuel in nuclear reactors and in bombs.

CRYSTALLOGRAPHIC DATA
base-centered orthorhombic

Crystal structure:

base-centered orthorhombic

Unit-cell dimensions / pm:

a=284.785, b=585.801, c=494.553

Space group:

Cmcm

 
PHYSICAL PROPERTIES

Density / g dm-3:18950 (293 K)

 17907 (m.p.)

Molar volume / cm3mol-1:12.56 (293 K)

 13.29 (m.p.)

Electrical resistivity / μΩcm:30 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:27.6

Melting point / °C:1135

Boiling point / °C:4131

Heat of fusion / kJ mol-1:15.5

Heat of vaporization / kJ mol-1:417.1

Heat of atomization / kJ mol-1:535.43

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:597.64

2nd ionization energy / kJ mol-1:-

3rd ionization energy / kJ mol-1:-

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:0.91

in the oceans / ppm:0.003

ISOTOPES
IsotopeRelative atomic massMass percent (%)
234U234.040946(2)0.0055(5)
235U235.043923(2)0.7200(12)
238U238.050783(2)99.2745(60)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
U4+ + e- = U3+- 0.607
U3+ + 3e- = U(s)- 1.798
UO22+ + e- = UO2++0.052
UO22+ + 3H+ + 2e- = UOH3+ + H2O+0.299
UO22+ + 4H+ + 2e- = U4+ + 2H2O+0.334
UO22+ + 2e- = UO2(s)+0.45
UO2+ + 3H+ + e- = UOH3+ + H2O+0.546
UO2+ + 4H+ + e- = U4+ + 2H2O+0.612
UOH3+ + H+ + e- = U3+ + H2O- 0.538
UO2(s) + 4H+ + 4e- = U(s) + 2H2O- 1.444
UO2(s) + 2H2O + 4e- = U(s) + 4OH-- 2.39
U3O8(s) + 4H+ + 4e- = 3UO2 + 2H2O+0.260
U(OH)3(s) + 3e- = U(s) + 3OH-- 2.17

 

91 Protactinium <= 92 Uranium => 93 Neptunium