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Periodic table

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Ruthenium

en  English

Ruthenium

fr  French

Ruthénium

hr  Croatian

Rutenij

it  Italian

Rutenio

es  Spanish

Rutenio

 

Ru
Ru
Ruthenium

PERIODIC TABLE OF THE ELEMENTS

RUTHENIUM

TRANSITION ELEMENT: IRON GROUP

 

Atomic number:44

Group numbers:8

Period:5

Electronic configuration:[Kr] 4d7 5s1

Formal oxidation number:+3

Electronegativities:2.2

Atomic radius / pm:132.5

Relative atomic mass:101.07 ± 0.02

 

Ruthenium was discovered by Karl Karlovich Klaus (RU) in 1844. The origin of the name comes from the Latin word Ruthenia meaning Russia. It is a rare, extremely brittle, silver-grey metal. Ruthenium is unaffected by air, water or acids but reacts with very hot (molten) alkalis. Ruthenium is found in pentlandite and pyroxinite. It is used to harden platinum and palladium, aircraft magnetos use platinum alloy with 10% ruthenium.

PHYSICAL PROPERTIES

Density / g dm-3:12370 (293 K)

 10900 (m.p.)

Molar volume / cm3mol-1:8.17 (293 K)

 9.27 (m.p.)

Electrical resistivity / μΩcm:7.6 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:117

Melting point / °C:2334

Boiling point / °C:4150

Heat of fusion / kJ mol-1:23.7

Heat of vaporization / kJ mol-1:567

Heat of atomization / kJ mol-1:641.031

IONIZATION ENERGIES

First ionization energy / kJ mol-1:710.19

Second ionization energy / kJ mol-1:1617.11

Third ionization energy / kJ mol-1:2746.96

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:0.01

in the oceans / ppm:-

CRYSTALLOGRAPHIC DATA

hexagonal

Crystal structure:

hexagonal

Unit-cell dimensions / pm:

a=270.58, c=428.11

Space group:

P63/mmc

ISOTOPES

IsotopeRelative atomic massMass percent (%)
96Ru95.907598(8)5.52(6)
98Ru97.905287(7)1.88(6)
99Ru98.905939(2)12.7(1)
100Ru99.904220(2)12.6(1)
101Ru100.905582(2)17.0(1)
102Ru101.904350(2)31.6(2)
104Ru103.905430(4)18.7(2)

REDUCTION POTENTIALS

Balanced half-reaction Eo / V
Ru2+ + 2e- = Ru(s)+0.45
RuO2(s) + 4H+ + 4e- = Ru(s) + 2H2O+0.79
RuO4(s) + e- = RuO4-+1.00
RuO4- + e- = RuO42-+0.59
RuCl5- + 2e- = Ru2+ + 5Cl-+0.3
RuCl3 + 3e- = Ru(s) + 3Cl-+0.68

 

43 Technetium <=
44 Ruthenium
=> 45 Rhodium