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Neighborhood
Nd
60
Pm
61
Sm
62
U
92
Np
93
Pu
94
 
 
 

 

Periodic table

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Neptunium

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Neptunium

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Neptunium

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Neptunij

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Nettunio

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Neptunio

 

Np
Np
Neptunium

PERIODIC TABLE OF THE ELEMENTS

NEPTUNIUM

TRANSITION ELEMENT:
ACTINIDE

 

Atomic number:93

Group numbers:3

Period:7

Electronic configuration:[Rn] 5f4 6d1 7s2

Formal oxidation number:+3 +4 +5 +6

Electronegativities:1.3

Atomic radius / pm:130

Relative atomic mass:[237]

 

Neptunium was discovered by Edwin Mattison McMillan and Philip Hauge Abelson (US) in 1940. Named after the planet Neptune. It is a rare, silvery radioactive, radiotoxic metal that resists alkalis, reacts with oxygen, acid and steam. Neptunium was produced by bombarding uranium with slow neutrons.

PHYSICAL PROPERTIES

Density / g dm-3:20250 (293 K)

Molar volume / cm3mol-1:11.70 (293 K)

Electrical resistivity / μΩcm:122 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:6.3

Melting point / °C:644

Boiling point / °C:3902

Heat of fusion / kJ mol-1:9.46

Heat of vaporization / kJ mol-1:336.6

Heat of atomization / kJ mol-1:457

IONIZATION ENERGIES

First ionization energy / kJ mol-1:604.55

Second ionization energy / kJ mol-1:-

Third ionization energy / kJ mol-1:-

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:-

in the oceans / ppm:-

CRYSTALLOGRAPHIC DATA

simple orthorhombic

Crystal structure:

simple orthorhombic

Unit-cell dimensions / pm:

a=472.3, b=488.7, c=666.3

Space group:

Pmcn

ISOTOPES

IsotopeRelative atomic massMass percent (%)
237Np237.048167(2)*

REDUCTION POTENTIALS

Balanced half-reaction Eo / V

 

92 Uranium <=
93 Neptunium
=> 94 Plutonium