Br
Br
Bromum
German
Brom
English
Bromine
French
Brome
Croatian
Brom
Italian
Bromo
Spanish
Bromo
Neighborhood
S
16
Cl
17
Ar
18
Se
34
Br
35
Kr
36
Te
52
I
53
Xe
54

PERIODIC TABLE OF THE ELEMENTS

BROMINE

HALOGENS ELEMENT

Atomic number:35

Group numbers:17

Period:4

Electronic configuration:[Ar] 3d10 4s2 4p5

Formal oxidation number:-1 +1 +5

Electronegativities:2.96

Atomic radius / pm:114.5

Relative atomic mass:79.904 ± 0.001

 

Bromine was discovered by Antoine-Jérôme Balard (FR) in 1826. The origin of the name comes from the Greek word bromos meaning stench. It is a reddish-brown liquid with suffocating, irritating fumes that gives off poisonous vapour. It is a oxidizer that causes severe burns. Bromine occurs in compounds in sea water. It was once used in large quantities to make a compound that removed lead compound build up in engines burning leaded gasoline. Now it is primarily used in dyes, disinfectants and photographic chemicals.

CRYSTALLOGRAPHIC DATA
base-centered orthorhombic

Crystal structure:

base-centered orthorhombic

Unit-cell dimensions / pm:

a=673.7, b=454.8, c=876.1

Space group:

Cmca

 
PHYSICAL PROPERTIES

Density / g dm-3:4050 (123 K)

 3122.6 (293 K)

 7.59 (gas, 273 K)

Molar volume / cm3mol-1:19.73 (123 K)

 25.59 (293 K)

 21055.07 (gas, 273 K)

Electrical resistivity / μΩcm:- (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:0.0047

Melting point / °C:-7.2

Boiling point / °C:58.78

Heat of fusion / kJ mol-1:10.8

Heat of vaporization / kJ mol-1:30.5

Heat of atomization / kJ mol-1:117.943

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:1139.87

2nd ionization energy / kJ mol-1:2103.40

3rd ionization energy / kJ mol-1:3473.50

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:2.5

in the oceans / ppm:65

ISOTOPES
IsotopeRelative atomic massMass percent (%)
79Br78.918338(2)50.69(7)
81Br80.916291(3)49.31(7)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
Br2(l) + 2e- = 2Br-+1.065
Br2(aq) + 2e- = 2Br-+1.087
Br3- + 2e- = 3Br-+1.05
HBrO3 + 5H+ + 6e- = Br- + 3H2O+1.42
3HBrO3 + 15H+ + 16e- = Br3- + 9H2O+1.462
2BrO3- + 12H+ + 10e- = Br2(l) + 6H2O+1.52
BrO3- + 6H+ + 6e- = Br- + 3H2O+1.44
BrO3- + 3H2O + 6e- = Br- + 6OH-+0.61
2HBrO2 + 10H+ + 10e- = Br2(l) + 6H2O+1.48
HBrO3 + 4H+ + 4e- = HBrO + 2H2O+1.46
HBrO3 + 3H+ + 4e- = BrO- + 2H2O+1.33
2HBrO + 2H+ + 2e- = Br2(l) + 2H2O+1.59
2BrO- + 4H+ + 2e- = Br2(l) + 2H2O+2.09
2BrO- + 2H2O + 2e- = Br2(l) + 4OH-+0.45
BrO- + H2O + 2e- = Br- + 2OH-+0.76

 

34 Selenium <= 35 Bromine => 36 Krypton