Cl
Cl
Chlorum
German
Chlor
English
Chlorine
French
Chlore
Croatian
Klor
Italian
Cloro
Spanish
Cloro
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O
8
F
9
Ne
10
S
16
Cl
17
Ar
18
Se
34
Br
35
Kr
36

PERIODIC TABLE OF THE ELEMENTS

CHLORINE

HALOGENS ELEMENT

Atomic number:17

Group numbers:17

Period:3

Electronic configuration:[Ne] 3s2 3p5

Formal oxidation number:-1 +1 +5 +7

Electronegativities:3.16

Atomic radius / pm:99.4

Relative atomic mass:35.453 ± 0.002

 

Chlorine was discovered by Carl William Scheele (SE) in 1774. The origin of the name comes from the Greek word chloros meaning pale green. It is a greenish-yellow, disagreeable gas with irritating odour. The gas is toxic and severe irritant by contact or inhalation. It's Never found in free form in nature. Commercial quantities of chlorine are produced by electrolysis of aqueous sodium chloride (NaCl) from seawater or brine from salt mines. Sulfur is used in water purification, bleaches, acids and many, many other compounds such as chlorofluorocarbons (CFC).

CRYSTALLOGRAPHIC DATA
base-centered orthorhombic

Crystal structure:

base-centered orthorhombic

Unit-cell dimensions / pm:

a=624, b=448, c=826

Space group:

Cmca

 
PHYSICAL PROPERTIES

Density / g dm-3:2030 (113 K)

 1507 (239 K)

 3.214 (273 K)

Molar volume / cm3mol-1:17.46 (113 K)

 23.53 (239 K)

 22061.61 (273 K)

Electrical resistivity / μΩcm:- (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:0.0089

Melting point / °C:-101.5

Boiling point / °C:-34.04

Heat of fusion / kJ mol-1:6.41

Heat of vaporization / kJ mol-1:20.4033

Heat of atomization / kJ mol-1:120

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:1251.20

2nd ionization energy / kJ mol-1:2297.72

3rd ionization energy / kJ mol-1:3821.81

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:130

in the oceans / ppm:19000

ISOTOPES
IsotopeRelative atomic massMass percent (%)
35Cl34.96885271(4)75.77(7)
37Cl36.96590260(5)24.23(7)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
Cl2(g) + 2e- = 2Cl-+1.359
Cl2(aq) + 2e- = 2Cl-+1.39
ClO4- + 2H+ + 2e- = ClO3- + H2O+1.19
ClO4- + H2O + 2e- = ClO3- + 2OH-+0.36
2ClO4- + 16H+ + 14e- = Cl2(g) + 8H2O+1.39
ClO3- + 3H+ + 2e- = HClO2 + H2O+1.21
ClO3- + H2O + 2e- = ClO2- + 2OH-+0.33
2ClO3- + 12H+ + 10e- = Cl2(g) + 3H2O+1.47
HClO2 + 2H+ + 2e- = HClO + H2O+1.64
ClO2- + H2O + 2e- = ClO- + 2OH-+0.66
2HClO + 2H+ + 2e- = Cl2(g) + H2O+1.63
2ClO- + 2H2O + 2e- = Cl2(g) + 4OH-+0.40

 

16 Sulphur <= 17 Chlorine => 18 Argon