Ir
Ir
Iridium
German
Iridium
English
Iridium
French
Iridium
Croatian
Iridij
Italian
Iridio
Spanish
Iridio
Neighborhood
Ru
44
Rh
45
Pd
46
Os
76
Ir
77
Pt
78
Hs
108
Mt
109
Ds
110

PERIODIC TABLE OF THE ELEMENTS

IRIDIUM

TRANSITION ELEMENT: COBALT GROUP

Atomic number:77

Group numbers:9

Period:6

Electronic configuration:[Xe] 4f14 5d7 6s2

Formal oxidation number:+3 +4

Electronegativities:2.2

Atomic radius / pm:135.7

Relative atomic mass:192.217 ± 0.003

 

Iridium was discovered by Smithson Tennant (GB) in 1803. The origin of the name comes from the Latin word iris, meaning rainbow, because its salts are highly coloured. It is a heavy, brittle, white metal that is unreactive in air, water and acids but reacts with fused NaOH. Metal ignites and burns readily. Iridium is found in gravel deposits with platinum. It is used with osmium to tip gold pen points, to make crucible and special containers, also to make alloys used for standard weights and measures and heat-resistant alloys. It is used as a hardening agent for platinum.

CRYSTALLOGRAPHIC DATA
face-centered cubic

Crystal structure:

face-centered cubic

Unit-cell dimensions / pm:

a=383.92

Space group:

Fm3m

 
PHYSICAL PROPERTIES

Density / g dm-3:22420 (290 K)

 20000 (m.p.)

Molar volume / cm3mol-1:8.57 (290 K)

 8.74 (m.p.)

Electrical resistivity / μΩcm:5.3 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:147

Melting point / °C:2446

Boiling point / °C:4428

Heat of fusion / kJ mol-1:26.4

Heat of vaporization / kJ mol-1:612.1

Heat of atomization / kJ mol-1:664.34

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:865.19

2nd ionization energy / kJ mol-1:-

3rd ionization energy / kJ mol-1:-

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:0.0001

in the oceans / ppm:-

ISOTOPES
IsotopeRelative atomic massMass percent (%)
191Ir190.960591(3)37.3(5)
193Ir192.962924(3)62.7(5)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
Ir3+ + 3e- = Ir(s)+1.15
IrCl62- + e- = IrCl63-+1.026
IrCl62- + 4e- = Ir(s) + 6Cl-+0.835
IrCl63- + 3e- = Ir(s) + 6Cl-+0.77
IrO2(s) + 4H+ + 4e- = Ir(s) + H2O+0.93
IrO2(s) + 2H2O + 4e- = Ir(s) + 4OH-+0.1
Ir2O3 + 3H2O + 6e- = 2Ir(s) + 6OH-+0.1

 

76 Osmium <= 77 Iridium => 78 Platinum