Ru
Ru
Ruthenium
German
Ruthenium
English
Ruthenium
French
Ruthénium
Croatian
Rutenij
Italian
Rutenio
Spanish
Rutenio
Neighborhood
Mn
25
Fe
26
Co
27
Tc
43
Ru
44
Rh
45
Re
75
Os
76
Ir
77

PERIODIC TABLE OF THE ELEMENTS

RUTHENIUM

TRANSITION ELEMENT: IRON GROUP

Atomic number:44

Group numbers:8

Period:5

Electronic configuration:[Kr] 4d7 5s1

Formal oxidation number:+3

Electronegativities:2.2

Atomic radius / pm:132.5

Relative atomic mass:101.07 ± 0.02

 

Ruthenium was discovered by Karl Karlovich Klaus (RU) in 1844. The origin of the name comes from the Latin word Ruthenia meaning Russia. It is a rare, extremely brittle, silver-grey metal. Ruthenium is unaffected by air, water or acids but reacts with very hot (molten) alkalis. Ruthenium is found in pentlandite and pyroxinite. It is used to harden platinum and palladium, aircraft magnetos use platinum alloy with 10% ruthenium.

CRYSTALLOGRAPHIC DATA
hexagonal

Crystal structure:

hexagonal

Unit-cell dimensions / pm:

a=270.58, c=428.11

Space group:

P63/mmc

 
PHYSICAL PROPERTIES

Density / g dm-3:12370 (293 K)

 10900 (m.p.)

Molar volume / cm3mol-1:8.17 (293 K)

 9.27 (m.p.)

Electrical resistivity / μΩcm:7.6 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:117

Melting point / °C:2334

Boiling point / °C:4150

Heat of fusion / kJ mol-1:23.7

Heat of vaporization / kJ mol-1:567

Heat of atomization / kJ mol-1:641.031

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:710.19

2nd ionization energy / kJ mol-1:1617.11

3rd ionization energy / kJ mol-1:2746.96

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:0.01

in the oceans / ppm:-

ISOTOPES
IsotopeRelative atomic massMass percent (%)
96Ru95.907598(8)5.52(6)
98Ru97.905287(7)1.88(6)
99Ru98.905939(2)12.7(1)
100Ru99.904220(2)12.6(1)
101Ru100.905582(2)17.0(1)
102Ru101.904350(2)31.6(2)
104Ru103.905430(4)18.7(2)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
Ru2+ + 2e- = Ru(s)+0.45
RuO2(s) + 4H+ + 4e- = Ru(s) + 2H2O+0.79
RuO4(s) + e- = RuO4-+1.00
RuO4- + e- = RuO42-+0.59
RuCl5- + 2e- = Ru2+ + 5Cl-+0.3
RuCl3 + 3e- = Ru(s) + 3Cl-+0.68

 

43 Technetium <= 44 Ruthenium => 45 Rhodium