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Thallium
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Cd
48
In
49
Sn
50
Hg
80
Tl
81
Pb
82
 
 
 

PERIODIC TABLE OF THE ELEMENTS

THALLIUM

BORON GROUP

Atomic number:81

Group numbers:13

Period:6

Electronic configuration:[Xe] 4f14 5d10 6s2 6p1

Formal oxidation number:+1 +3

Electronegativities:1.8

Atomic radius / pm:170

Relative atomic mass:204.3833 ± 0.0002

 

Thallium was discovered by Sir William Crookes (GB) in 1861. The origin of the name comes from the Greek word thallos meaning green twig or green shoot. It is a soft grey metal that looks like lead and tarnishes in moist air. Thallium reacts in heated moist air and in acids. Its compounds are highly toxic by inhalation or ingestion and have a cumulative effect. Thallium is found in iron pyrites, in crookesite, hutchinsonite and lorandite. Most is recovered from the by-products of lead and zinc refining. Its compounds are used in rat and ant poisons and for detecting infrared radiation.

CRYSTALLOGRAPHIC DATA
hexagonal

Crystal structure:

hexagonal

Unit-cell dimensions / pm:

a=345.6, c=552.6

Space group:

P63/mmc

 
PHYSICAL PROPERTIES

Density / g dm-3:11850 (293 K)

 11290 (m.p.)

Molar volume / cm3mol-1:17.25 (293 K)

 18.10 (m.p.)

Electrical resistivity / μΩcm:18 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:46.1

Melting point / °C:304

Boiling point / °C:1473

Heat of fusion / kJ mol-1:4.31

Heat of vaporization / kJ mol-1:166.1

Heat of atomization / kJ mol-1:182.845

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:589.36

2nd ionization energy / kJ mol-1:1971.02

3rd ionization energy / kJ mol-1:2878.18

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:0.36

in the oceans / ppm:0.00001

ISOTOPES
IsotopeRelative atomic massMass percent (%)
203Tl202.972329(3)29.524(14)
205Tl204.974412(3)70.476(14)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
Tl3+ + 2e- = Tl++1.25
Tl+ + e- = Tl(s)- 0.336
Tl2O3 + 3H2O + 4e- = 2Tl+ + 6OH-+0.02
TlOH + e- = Tl(s) + OH-- 0.344
TlCl(s) + e- = Tl(s) + Cl-- 0.557
TlBr(s) + e- = Tl(s) + Br-- 0.657
TlI(s) + e- = Tl(s) + I-- 0.766

 

80 Mercury <= 81 Thallium => 82 Lead