Sn
Sn
Stannum
German
Zinn
English
Tin
French
Etain
Croatian
Kositar
Italian
Stagno
Spanish
Estaño
Neighborhood
Ga
31
Ge
32
As
33
In
49
Sn
50
Sb
51
Tl
81
Pb
82
Bi
83

Atomic number:50

Group numbers:14

Period:5

Electronic configuration:[Kr] 4d10 5s2 5p2

Formal oxidation number:+2 +4

Electronegativities:1.96

Atomic radius / pm:140.5

Relative atomic mass:118.710 ± 0.007

 

Tin has been known since ancient times. The origin of the name comes from the Latin word stannum meaning tin. It is a silvery-white, soft, malleable and ductile metal that ressist oxygen and water but dissolves in acids and bases. Exposed surfaces form oxide film. Organic tin compounds may be highly toxic. Tin is principally found in the ore cassiterite (SnO2) and stannine (Cu2FeSnS4). It is used as a coating for steel cans since it is non-toxic and non-corrosive, also in solder (33%Sn:67%Pb), bronze (20%Sn:80%Cu) and pewter. Stannous fluoride (SnF2), a compound of tin and fluorine is used in some toothpaste.

CRYSTALLOGRAPHIC DATA
body-centered tetragonal

Crystal structure:

body-centered tetragonal

Unit-cell dimensions / pm:

a=583.16, c=318.13

Space group:

I42/amd

 
PHYSICAL PROPERTIES

Density / g dm-3:5750 (alpha, 273 K)

 7310 (beta, 273 K)

 6973 (m.p.)

Molar volume / cm3mol-1:20.65 (alpha, 273 K)

 16.24 (beta, 273 K)

 17.02 (m.p.)

Electrical resistivity / μΩcm:11 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:66.6

Melting point / °C:231.928

Boiling point / °C:2602

Heat of fusion / kJ mol-1:7.2

Heat of vaporization / kJ mol-1:296.2

Heat of atomization / kJ mol-1:302

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:708.58

2nd ionization energy / kJ mol-1:1411.81

3rd ionization energy / kJ mol-1:2943.07

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:2.5

in the oceans / ppm:0.003

ISOTOPES
IsotopeRelative atomic massMass percent (%)
112Sn111.904821(5)0.97(1)
114Sn113.902782(3)0.65(1)
115Sn114.903346(3)0.34(1)
116Sn115.901744(3)14.53(1)
117Sn116.902954(3)7.68(7)
118Sn117.901606(3)24.23(11)
119Sn118.903309(3)8.59(4)
120Sn119.902197(3)32.59(10)
122Sn121.903440(3)4.63(3)
124Sn123.905275(1)5.79(5)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
Sn4+ + 2e- = Sn2++0.154
Sn4+ + 2e- = Sn2++0.14 (1 mol dm-3 HCl)
Sn4+ + 4e- = Sn(s)+0.01
Sn2+ + 2e- = Sn(s)- 0.136
Sn2+ + 2e- = Sn(s)- 0.16 (1 mol dm-3 HClO4)
SnO32- + 3H+ + 2e- = HSnO2- + H2O+0.374
SnO32- + 6H+ + 2e- = Sn2+ + 3H2O+0.844
HSnO2- + 3H+ + 2e- = Sn(s) + 2H2O+0.333
Sn(s) + 4H+ + 4e- = SnH4(g)- 1.074

 

49 Indium <= 50 Tin => 51 Antimony