Fe
Fe
Ferrum
German
Eisen
English
Iron
French
Fer
Croatian
Željezo
Italian
Ferro
Spanish
Hierro
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Mn
25
Fe
26
Co
27
Tc
43
Ru
44
Rh
45

PERIODIC TABLE OF THE ELEMENTS

IRON

TRANSITION ELEMENT: IRON GROUP

Atomic number:26

Group numbers:8

Period:4

Electronic configuration:[Ar] 3d6 4s2

Formal oxidation number:+2 +3

Electronegativities:1.83

Atomic radius / pm:124.1

Relative atomic mass:55.845 ± 0.002

 

Iron has been known since ancient times. The origin of the name comes from the Latin word ferrum meaning iron. It is a malleable, ferromagnetic, ductile, silvery-white metal. Exposed surfaces form red-brown oxides. Iron forms very strong alloys (steel). Iron dust flammable. It's the Fourth most abundant element in the earth's crust. Iron is obtained from iron ores. Pure metal is produced in blast furnaces by layering limestone, coke and iron ore and forcing hot gasses into the bottom. This heats the coke red hot and the iron is reduced from its oxides and liquefied where it flows to the bottom. Iron is the most common metal in human society. More than 90% of all metal refined in the world is iron. It is used in steel and other alloys. Iron is the chief constituent of hemoglobin which carries oxygen in blood vessels. It's oxides are used in magnetic tapes and disks.

CRYSTALLOGRAPHIC DATA
body-centered cubic

Crystal structure:

body-centered cubic

Unit-cell dimensions / pm:

a=286.645

Space group:

Im3m

 
PHYSICAL PROPERTIES

Density / g dm-3:7874 (293 K)

 7035 (m.p.)

Molar volume / cm3mol-1:7.09 (293 K)

 7.94 (m.p.)

Electrical resistivity / μΩcm:9.71 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:80.2

Melting point / °C:1538

Boiling point / °C:2861

Heat of fusion / kJ mol-1:14.9

Heat of vaporization / kJ mol-1:340.2

Heat of atomization / kJ mol-1:413.96

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:762.47

2nd ionization energy / kJ mol-1:1561.90

3rd ionization energy / kJ mol-1:2957.49

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:70700

in the oceans / ppm:0.01

ISOTOPES
IsotopeRelative atomic massMass percent (%)
54Fe53.939615(1)5.8(1)
56Fe55.934942(1)91.72(30)
57Fe56.935399(1)2.1(1)
58Fe57.933280(1)0.28(1)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
Fe3+ + 3e- = Fe(s)- 0.04
Fe3+ + e- = Fe2++0.771
Fe3+ + e- = Fe2++0.700 (1 mol dm-3 HCl)
Fe3+ + e- = Fe2++0.732 (1 mol dm-3 HClO4)
Fe3+ + e- = Fe2++0.68 (1 mol dm-3 H2SO4)
Fe2+ + 2e- = Fe(s)- 0.440
FeOH2+ + H+ + e- = Fe2+ + H2O+0.91
Fe(OH)2+ + 2H+ + e- = Fe2+ + 2H2O+1.19
FeO42- + 8H+ + 3e- = Fe3+ + 4H2O+1.70
FeO42- + 7H+ + 3e- = FeOH2+ + 3H2O+1.65
FeO42- + 6H+ + 3e- = Fe(OH)2+ + 2H2O+1.56
FeO42- + 5H+ + 3e- = HFeO2 + 2H2O+1.00
HFeO2- + 3H+ + 2e- = Fe(s) + 2H2O+0.49
Fe(CN)63- + e- = Fe(CN)64-+0.36
Fe(CN)63- + e- = Fe(CN)64-+0.71 (1 mol dm-3 HCl)
Fe(CN)63- + e- = Fe(CN)64-+0.72 (1 mol dm-3 HClO4)
Fe(CN)63- + e- = Fe(CN)64-+0.72 (1 mol dm-3 H2SO4)
Fe(C12H8N2)33+ + e- = Fe(C12H8N2)32++1.06

 

25 Manganese <= 26 Iron => 27 Cobalt