Mo
Mo
Molybdenum
German
Molybdän
English
Molybdenum
French
Molybdène
Croatian
Molibden
Italian
Molibdeno
Spanish
Molibdeno
Neighborhood
V
23
Cr
24
Mn
25
Nb
41
Mo
42
Tc
43
Ta
73
W
74
Re
75

PERIODIC TABLE OF THE ELEMENTS

MOLYBDENUM

TRANSITION ELEMENT: CHROMIUM GROUP

Atomic number:42

Group numbers:6

Period:5

Electronic configuration:[Kr] 4d5 5s1

Formal oxidation number:+6

Electronegativities:2.16

Atomic radius / pm:136.3

Relative atomic mass:95.94 ± 0.02

 

Molybdenum was discovered by Carl William Scheele (SE) in 1778. The origin of the name comes from the Greek word molybdos meaning lead. It is a silvery white, very hard metal, but is softer and more ductile than tungsten. Molybdenum is found in the minerals molybdenite (MoS2) and wulfenite (MoO4Pb). Its alloys are used in aircraft, missiles and protective coatings in boiler plate.

CRYSTALLOGRAPHIC DATA
body-centered cubic

Crystal structure:

body-centered cubic

Unit-cell dimensions / pm:

a=314.700

Space group:

Im3m

 
PHYSICAL PROPERTIES

Density / g dm-3:10220 (293 K)

 9330 (m.p.)

Molar volume / cm3mol-1:9.39 (293 K)

 10.28 (m.p.)

Electrical resistivity / μΩcm:5.34 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:138

Melting point / °C:2623

Boiling point / °C:4639

Heat of fusion / kJ mol-1:27.6

Heat of vaporization / kJ mol-1:589.9

Heat of atomization / kJ mol-1:656.55

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:684.32

2nd ionization energy / kJ mol-1:1559.21

3rd ionization energy / kJ mol-1:2617.67

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:1

in the oceans / ppm:0.01

ISOTOPES
IsotopeRelative atomic massMass percent (%)
92Mo91.906810(4)14.84(4)
94Mo93.905088(2)9.25(3)
95Mo94.905841(2)15.92(5)
96Mo95.904679(2)16.68(5)
97Mo96.906021(2)9.55(3)
98Mo97.905408(2)24.13(7)
100Mo99.907477(6)9.63(3)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
MoVI + e- = MoV+0.43 (4.6 mol dm-3 H2SO4)
MoIII + 3e- = Mo(s)- 0.2
H2MoO4(aq) + 2H+ + e- = MoO2+ + 2H2O+0.4
HMoO4- + 3H+ + 2e- = MoO2 + 2H2O+0.429
MoO42- + 4H+ + 2e- = MoO2 + 2H2O+0.606
HMoO4- + 7H+ + 3e- = Mo3+ + 4H2O+0.390
MoO42- + 8H+ + 3e- = Mo3+ + 4H2O+0.508
MoO42- + 8H+ + 6e- = Mo(s) + 4H2O+0.154
MoO42- + 4H2O + 6e- = Mo(s) + 8OH-- 1.05

 

41 Niobium <= 42 Molybdenum => 43 Technetium