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Nb
41
Mo
42
Tc
43
Ta
73
W
74
Re
75
Db
105
Sg
106
Bh
107

PERIODIC TABLE OF THE ELEMENTS

TUNGSTEN

TRANSITION ELEMENT: CHROMIUM GROUP

Atomic number:74

Group numbers:6

Period:6

Electronic configuration:[Xe] 4f14 5d4 6s2

Formal oxidation number:+6

Electronegativities:1.7

Atomic radius / pm:137

Relative atomic mass:183.84 ± 0.01

 

Tungsten was discovered by Fausto and Juan Jose de Elhuyar (ES) in 1783. Named after the tungsten mineral wolframite. It is a hard, steel-grey to white metal that has the highest melting point of all metals. Tungesten resists oxygen, acids and alkalis. Tungsten occurs in the minerals scheelite (CaWO4) and wolframite [(Fe,Mn)WO4]. It is made into filaments for vacuum tubes and electric lights it can also be used as contact points in cars. Tungsten carbide is extremely hard and is used for making cutting tools and abrasives.

CRYSTALLOGRAPHIC DATA
body-centered cubic

Crystal structure:

body-centered cubic

Unit-cell dimensions / pm:

a=316.522

Space group:

Im3m

 
PHYSICAL PROPERTIES

Density / g dm-3:19300 (293 K)

 17700 (m.p.)

Molar volume / cm3mol-1:9.53 (293 K)

 10.39 (m.p.)

Electrical resistivity / μΩcm:5.4 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:174

Melting point / °C:3422

Boiling point / °C:5555

Heat of fusion / kJ mol-1:35.2

Heat of vaporization / kJ mol-1:824.2

Heat of atomization / kJ mol-1:848.1

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:758.77

2nd ionization energy / kJ mol-1:-

3rd ionization energy / kJ mol-1:-

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:1

in the oceans / ppm:0.000001

ISOTOPES
IsotopeRelative atomic massMass percent (%)
180W179.946706(5)0.13(4)
182W181.948206(3)26.3(2)
183W182.950224(3)14.3(1)
184W183.950933(3)30.67(15)
186W185.954362(3)28.6(2)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
2WO3(s) + 2H+ + 2e- = W2O5(s) + H2O- 0.029
WO3(s) + 6H+ + 6e- = W(s) + 3H2O- 0.09
2WO42- + 6H+ + 2e- = W2O5(s) + 3H2O+0.801
WO42- + 4H+ + e- = WO2(s) + 2H2O+0.386
WO42- + 8H+ + 6e- = W(s) + 4H2O+0.049
W2O5(s) + 2H+ + 2e- = 2WO2(s) + H2O- 0.031
WO2(s) + 4H+ + 4e- = W(s) + 2H2O- 0.12
W(CN)83- + e- = W(CN)84-+0.457

 

73 Tantalum <= 74 Tungsten => 75 Rhenium