Sb
Sb
Stibium
German
Antimon
English
Antimony
French
Antimoine
Croatian
Antimon
Italian
Antimonio
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Ge
32
As
33
Se
34
Sn
50
Sb
51
Te
52
Pb
82
Bi
83
Po
84

PERIODIC TABLE OF THE ELEMENTS

ANTIMONY

NITROGEN GROUP

Atomic number:51

Group numbers:15

Period:5

Electronic configuration:[Kr] 4d10 5s2 5p3

Formal oxidation number:-3 +3 +5

Electronegativities:2.05

Atomic radius / pm:145

Relative atomic mass:121.760 ± 0.001

 

Antimony has been known since ancient times. The origin of the name comes from the Latin word stibium meaning mineral stibnite. It is a hard, brittle, silvery-white semimetal that is stable in dry air. It is toxic by ingestion or inhalation. Antimony is found in stibnite (Sb2S3) and in valentinite (Sb2O3). It is alloyed with other metals to increase their hardness. It is used in the manufacture of a few special types of semiconductor devices, also in plastics and chemicals. A few kinds of over-the-counter cold and flu remedies use antimony compounds.

CRYSTALLOGRAPHIC DATA
rhombohedral

Crystal structure:

rhombohedral

Unit-cell dimensions / pm:

a=430.84, c=1124.7

Space group:

R3m

 
PHYSICAL PROPERTIES

Density / g dm-3:6691 (293 K)

 6483 (m.p.)

Molar volume / cm3mol-1:18.20 (293 K)

 18.78 (m.p.)

Electrical resistivity / μΩcm:39 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:24.3

Melting point / °C:630.63

Boiling point / °C:1587

Heat of fusion / kJ mol-1:20.9

Heat of vaporization / kJ mol-1:165.8

Heat of atomization / kJ mol-1:262.04

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:830.59

2nd ionization energy / kJ mol-1:1594.96

3rd ionization energy / kJ mol-1:2441.10

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:0.2

in the oceans / ppm:0.0005

ISOTOPES
IsotopeRelative atomic massMass percent (%)
121Sb120.903818(2)57.36(8)
123Sb122.904216(2)42.64(8)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
SbV + 2e- = SbIII+0.818 (6 mol dm-3 HCl)
SbV + 2e- = SbIII+0.746 (3.5 mol dm-3 HCl)
SbO+ + 2H+ + 3e- = Sb(s) + H2O+0.212
SbO3- + 2H+ + 2e- = SbO2- + H2O+0.353
SbO3- + 3H+ + 2e- = HSbO2 + H2O+0.678
SbO3- + 4H+ + 2e- = SbO+ + 2H2O+0.704
SbO2- + 2H+ + 2e- = SbO- + H2O+0.720
2SbO3- + 6H+ + 4e- = Sb2O3(s) + 3H2O+0.772
SbO2- + 4H+ + 3e- = Sb(s) + 2H2O+0.446
HSbO2 + 3H+ + 3e- = Sb(s) + 2H2O+0.230
Sb2O3(s) + 6H+ + 6e- = 2Sb(s) + 3H2O+0.152
Sb2O5(s) + 6H+ + 4e- = 2SbO+ + 3 H2O+0.581
Sb2O5(s) + 4H+ + 4e- = Sb2O3(s) + 2H2O+0.692
Sb(s) + 3H+ + 3e- = SbH3(g)- 0.510

 

50 Tin <= 51 Antimony => 52 Tellurium