Ge
Ge
Germanium

 

Germanium
Germanium
Germanium
Germanij
Germanio
Germanio
Neighborhood
Al
13
Si
14
P
15
Ga
31
Ge
32
As
33
In
49
Sn
50
Sb
51

PERIODIC TABLE OF THE ELEMENTS

GERMANIUM

CARBON GROUP

Atomic number:32

Group numbers:14

Period:4

Electronic configuration:[Ar] 3d10 4s2 4p2

Formal oxidation number:+2 +4

Electronegativities:2.01

Atomic radius / pm:122.5

Relative atomic mass:72.64 ± 0.01

 

Germanium was discovered by Clemens Alexander Winkler (DE) in 1886. The origin of the name comes from the Latin word Germania meaning Germany. It is a greyish-white semi-metal, stable in air and water. Germanium is unaffected by alkalis and most (except nitric) acids. Germanium is obtained from refining copper, zinc and lead. It is widely used in semiconductors when combined with tiny amounts of phosphorus, arsenic, gallium and antimony.

CRYSTALLOGRAPHIC DATA
face-centered cubic

Crystal structure:

face-centered cubic

Unit-cell dimensions / pm:

a=565.754

Space group:

Fd3m

 
PHYSICAL PROPERTIES

Density / g dm-3:5323 (293 K)

 5490 (m.p.)

Molar volume / cm3mol-1:13.65 (293 K)

 13.23 (m.p.)

Electrical resistivity / μΩcm:46000000 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:59.9

Melting point / °C:938.25

Boiling point / °C:2833

Heat of fusion / kJ mol-1:34.7

Heat of vaporization / kJ mol-1:327.6

Heat of atomization / kJ mol-1:373.8

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:762.18

2nd ionization energy / kJ mol-1:1537.47

3rd ionization energy / kJ mol-1:3302.15

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:1.6

in the oceans / ppm:0.0001

ISOTOPES
IsotopeRelative atomic massMass percent (%)
70Ge69.924250(2)21.23(4)
72Ge71.922076(2)27.66(3)
73Ge72.923459(2)7.73(1)
74Ge73.921178(2)35.94(2)
76Ge75.921403(2)7.44(2)
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
Ge2+ + 2e- = Ge(s)+0.00
GeO2(s) + 4H+ + 2e- = Ge2+ + 2H2O- 0.25
GeO2(s) + 4H+ + 4e- = Ge + 2H2O- 0.01
H2GeO3 + 4H+ + 4e- = Ge(s) + 3H2O- 0.13
GeO(s) + 2H+ + 2e- = Ge(s) + H2O- 0.29

 

31 Gallium <= 32 Germanium => 33 Arsenic