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Neighborhood
Cd
48
In
49
Sn
50
Hg
80
Tl
81
Pb
82
Cn
112
 
 

 

Periodic table

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Thallium

en  English

Thallium

fr  French

Thallium

hr  Croatian

Talij

it  Italian

Tallio

es  Spanish

Talio

 

Tl
Tl
Thallium

PERIODIC TABLE OF THE ELEMENTS

THALLIUM

BORON GROUP

 

Atomic number:81

Group numbers:13

Period:6

Electronic configuration:[Xe] 4f14 5d10 6s2 6p1

Formal oxidation number:+1 +3

Electronegativities:1.8

Atomic radius / pm:170

Relative atomic mass:204.3833 ± 0.0002

 

Thallium was discovered by Sir William Crookes (GB) in 1861. The origin of the name comes from the Greek word thallos meaning green twig or green shoot. It is a soft grey metal that looks like lead and tarnishes in moist air. Thallium reacts in heated moist air and in acids. Its compounds are highly toxic by inhalation or ingestion and have a cumulative effect. Thallium is found in iron pyrites, in crookesite, hutchinsonite and lorandite. Most is recovered from the by-products of lead and zinc refining. Its compounds are used in rat and ant poisons and for detecting infrared radiation.

PHYSICAL PROPERTIES

Density / g dm-3:11850 (293 K)

 11290 (m.p.)

Molar volume / cm3mol-1:17.25 (293 K)

 18.10 (m.p.)

Electrical resistivity / μΩcm:18 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:46.1

Melting point / °C:304

Boiling point / °C:1473

Heat of fusion / kJ mol-1:4.31

Heat of vaporization / kJ mol-1:166.1

Heat of atomization / kJ mol-1:182.845

IONIZATION ENERGIES

First ionization energy / kJ mol-1:589.36

Second ionization energy / kJ mol-1:1971.02

Third ionization energy / kJ mol-1:2878.18

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:0.36

in the oceans / ppm:0.00001

CRYSTALLOGRAPHIC DATA

hexagonal

Crystal structure:

hexagonal

Unit-cell dimensions / pm:

a=345.6, c=552.6

Space group:

P63/mmc

ISOTOPES

IsotopeRelative atomic massMass percent (%)
203Tl202.972329(3)29.524(14)
205Tl204.974412(3)70.476(14)

REDUCTION POTENTIALS

Balanced half-reaction Eo / V
Tl3+ + 2e- = Tl++1.25
Tl+ + e- = Tl(s)- 0.336
Tl2O3 + 3H2O + 4e- = 2Tl+ + 6OH-+0.02
TlOH + e- = Tl(s) + OH-- 0.344
TlCl(s) + e- = Tl(s) + Cl-- 0.557
TlBr(s) + e- = Tl(s) + Br-- 0.657
TlI(s) + e- = Tl(s) + I-- 0.766

 

80 Mercury <=
81 Thallium
=> 82 Lead