P
P
Phosphor
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C
6
N
7
O
8
Si
14
P
15
S
16
Ge
32
As
33
Se
34

PERIODIC TABLE OF THE ELEMENTS

PHOSPHORUS

NITROGEN GROUP

Atomic number:15

Group numbers:15

Period:3

Electronic configuration:[Ne] 3s2 3p3

Formal oxidation number:-3 +3 +5

Electronegativities:2.19

Atomic radius / pm:110.5

Relative atomic mass:30.973762 ± 0.000002

 

Phosphorus was discovered by Hennig Brandt (DE) in 1669. The origin of the name comes from the Greek word phosphoros meaning bringer of light. White phosphorus is white to yellow soft, waxy phosphorescent solid with acrid fumes. It's Toxic by inhalation, ingestion, or skin contact. Red phosphorus is powdery, non-flammable and non-toxic. Phosphorus is most often found in phosphate rock. Pure form is obtained by heating a mixture of phosphate rock, coke and silica to about 1450 °C. It is used in the production of fertilizers and detergents. Some is used in fireworks, safety matches and incendiary weapons. Phosphorus is also important in the production of steels, phosphor bronze and many other products.

CRYSTALLOGRAPHIC DATA
simple cubic

Crystal structure:

simple cubic

Unit-cell dimensions / pm:

a=1131

Space group:

Pm3m

 
PHYSICAL PROPERTIES

Density / g dm-3:1820 (white, 293 K)

 2200 (red, 293 K)

 2690 (black, 293 K)

Molar volume / cm3mol-1:17.02 (white, 293 K)

 14.08 (red, 293 K)

 11.51 (black, 293 K)

Electrical resistivity / μΩcm:1E+17 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:0.235

Melting point / °C:44.15

Boiling point / °C:280.5

Heat of fusion / kJ mol-1:2.51

Heat of vaporization / kJ mol-1:51.9

Heat of atomization / kJ mol-1:314

IONIZATION ENERGIES

1st ionization energy / kJ mol-1:1011.82

2nd ionization energy / kJ mol-1:1907.47

3rd ionization energy / kJ mol-1:2914.14

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:1050

in the oceans / ppm:0.07

ISOTOPES
IsotopeRelative atomic massMass percent (%)
31P30.9737615(2)100
REDUCTION POTENTIALS
Balanced half-reaction Eo / V
PO43- + 3H+ + 2e- = HPO32- + H2O+0.121
HPO42- + 2H+ + 2e- = HPO32- + H2O- 0.234
H2PO4- + H+ + 2e- = HPO32- + H2O- 0.447
H2PO4- + 2H+ + 2e- = H2PO3- + H2O- 0.260
H3PO4 + H+ + 2e- = H2PO3- + H2O- 0.329
H3PO4 + 2H+ + 2e- = H3PO3 + H2O- 0.276
PO43- + 8H+ + 5e- = P (red) + 4H2O- 0.128
PO43- + 8H+ + 5e- = P (white) + 4H2O- 0.156
HPO42- + 7H+ + 5e- = P (red) + 4H2O- 0.288
HPO42- + 7H+ + 5e- = P (white) + 4H2O- 0.316
H2PO4- + 6H+ + 5e- = P (red) + 4H2O- 0.358
H2PO4- + 6H+ + 5e- = P (white) + 4H2O- 0.386
H3PO4 + 5H+ + 5e- = P (red) + 4H2O- 0.383
H3PO4 + 5H+ + 5e- = P (white) + 4H2O- 0.411
PO43- + 11H+ + 8e- = PH3(g) + 4H2O- 0.123
HPO42- + 10H+ + 8e- = PH3(g) + 4H2O- 0.212
H2PO4- + 9H+ + 8e- = PH3(g) + 4H2O- 0.265
H3PO4 + 8H+ + 8e- = PH3(g) + 4H2O- 0.281
H3PO3 + 2H+ + 2e- = H3PO2 + H2O- 0.499
HPO32- + 5H+ + 3e- = P (red) + 3H2O- 0.298
HPO32- + 5H+ + 3e- = P (white) + 3H2O- 0.346
H2PO3- + 4H+ + 3e- = P (red) + 3H2O- 0.419
H2PO3- + 4H+ + 3e- = P (white) + 3H2O- 0.467
H3PO3 + 3H+ + 3e- = P (red) + 3H2O- 0.454
H3PO3 + 3H+ + 3e- = P (white) + 3H2O- 0.502
H4P2O6 + 2H+ + 2e- = 2H3PO3+0.38
2H3PO4 + 2H+ + 2e- = H4P2O6 + 2H2O- 0.94
P (red) + 3H+ + 3e- = PH3(g)- 0.111
P (white) + 3H+ + 3e- = PH3(g)- 0.063

 

14 Silicon <= 15 Phosphorus => 16 Sulphur