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Al
13
Cu
29
Zn
30
Ga
31
Ag
47
Cd
48
In
49

 

Periodic table

 

Zn
Zn
Zincum

PERIODIC TABLE OF THE ELEMENTS

ZINC

TRANSITION ELEMENT: ZINC GROUP

 

Atomic number:30

Group numbers:12

Period:4

Electronic configuration:[Ar] 3d10 4s2

Formal oxidation number:+2

Electronegativities:1.65

Atomic radius / pm:133.5

Relative atomic mass:65.38 ± 0.02

 

Zinc has been known since ancient times. The origin of the name comes from the German word zink. It is a bluish-silver, ductile metal that reacts with alkalis and acids. Zinc tarnishes in air. Zinc is found in the minerals zinc blende (sphalerite) (ZnS), calamine, franklinite, smithsonite (ZnCO3), willemite and zincite (ZnO). It is used to coat other metal (galvanizing) to protect them from rusting, 90% of the zinc is used for galvanizing steel. Zinc metal is used in the common dry-cell batteries and to make alloys such as brass, bronze. Zinc compounds are used in the manufacture of paints, cosmetics, plastics, electronic devices, and many other products.

PHYSICAL PROPERTIES

Density / g dm-3:7133 (293 K)

 6577 (m.p.)

Molar volume / cm3mol-1:9.17 (293 K)

 9.94 (m.p.)

Electrical resistivity / μΩcm:5.964 (20 °C)

THERMAL PROPERTIES

Thermal conductivity / W m-1K-1:116

Melting point / °C:419.53

Boiling point / °C:907

Heat of fusion / kJ mol-1:6.67

Heat of vaporization / kJ mol-1:114.2

Heat of atomization / kJ mol-1:130.181

IONIZATION ENERGIES

First ionization energy / kJ mol-1:906.41

Second ionization energy / kJ mol-1:1733.31

Third ionization energy / kJ mol-1:3832.71

ABUNDANCE OF ELEMENTS

in the atmosphere / ppm:-

in the Earth's crust / ppm:80

in the oceans / ppm:0.01

CRYSTALLOGRAPHIC DATA

hexagonal

Crystal structure:

hexagonal

Unit-cell dimensions / pm:

a=266.47, c=494.69

Space group:

P63/mmc

ISOTOPES

IsotopeRelative atomic massMass percent (%)
64Zn63.929147(2)48.6(3)
66Zn65.926037(2)27.9(2)
67Zn66.927131(2)4.1(1)
68Zn67.924848(2)18.8(4)
70Zn69.925325(4)0.6(1)

REDUCTION POTENTIALS

Balanced half-reaction Eo / V
Zn2+ + 2e- = Zn(s)- 0.763
ZnO22- + 4H+ + 2e- = Zn(s) + 2H2O+0.441
HZnO2- + 3H+ + 2e- = Zn(s) + 2H2O- 0.054
ZnO22- + 2H2O + 2e- = Zn(s) + 4OH-- 1.216
Zn(OH)2(s) + 2e- = Zn(s) + 2OH-- 1.245
ZnS(s) + 2e- = Zn(s) + S2-- 1.40
Zn(NH3)42+ + 2e- = Zn(s) + 4NH3- 1.04
Zn(CN)42+ + 2e- = Zn(s) + 4CN-- 1.26

 

29 Copper <=
30 Zinc
=> 31 Gallium